Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride
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چکیده
منابع مشابه
Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride
Reinvestigation of the Lewis acid catalyzed rearrangement of some open-chain permethyloligosilanes with the Al(Fe)Cl(3) catalyst system exhibited several cases of additional reactivity: namely, a fragmentation/cyclization reaction. Introduction of (trimethylsilyl)methyl substituents into the oligosilane substrates strongly facilitated this reaction, yielding cyclic or bicyclic carbacyclosilanes...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2011
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om1011165